Line-broadening effects in the powder infrared spectrum of apatite

The crystallinity of natural and synthetic apatite samples is often determined from the broadening of ν ₄ PO₄ infrared absorption bands. However, various physical mechanisms contribute to the observed linewidth. In the present study, the factors determining the linewidth in the powder spectrum of synthetic fluorapatite and hydroxyapatite samples are investigated. The temperature dependence of the infrared spectrum (10–270 K) is used to assess the respective contributions of homogeneous broadening, related to the decay of phonons through anharmonic coupling, and heterogeneous broadening related to elastic strain and macroscopic electrostatic effects. This latter contribution is dominant in the investigated samples and depends on the shape of powder particles. It is discussed under the light of the theoretical modeling of the low-frequency dielectric properties of apatite based on first-principles density functional theory calculations. The linewidth of the weak ν ₁ PO₄ absorption band provides a reliable information on microscopic sources of broadening, i.e., apatite crystallinity. In comparison, the other more intense PO₄ bands are more sensitive to long-range electrostatic effects.     

Why are climate policies of the present decade so crucial for keeping the 2 °C target credible?

Decision-makers have confirmed the long term objective of preventing a temperature increase greater than 2 °C. This paper aims at appraising by means of a cost-benefit analysis whether decision makers’ commitment to meet the 2 °C objective is credible or not. Within the framework of a cost-benefit type integrated assessment model, we consider that the economy faces climate damages with a threshold at 2 °C. We run the model for a broad set of scenarios accounting for the diversity of “worldviews” in the climate debate. For a significant share of scenarios we observe that it is considered optimal to exceed the threshold. Among those “non-compliers” we discriminate ”involuntary non-compliers” who cannot avoid the exceedance due to physical constraint from ”deliberate compliers” for whom the exceedance results from a deliberate costs-benefit analysis. A second result is that the later mitigation efforts begin, the more difficult it becomes to prevent the exceedance. In particular, the number of ”deliberate non-compliers” dramatically increases if mitigation efforts do not start by 2020, and the influx of involuntary non-compliers become overwhelming f efforts are delayed to 2040. In light of these results we argue that the window of opportunity for reaching the 2 °C objective with a credible chance of success is rapidly closing during the present decade. Further delay in finding a climate agreement critically undermines the credibility of the objective.     

No Development,No Conservation: Elements from the Conservation of Farm Animal Genetic Resources

Using concrete examples of conservation of farm animal genetic resources, we show that conservation and development should not be considered as two opposing processes. On the contrary, their synergies can facilitate conservation dynamics. We discuss conservation and development dynamics, and provide examples of synergies between the two dynamics to underline how development dynamics can help conservation programs.     

Influence of sample location and livestock numbers on Sporormiella concentrations and accumulation rates in surface sediments of Lake Allos, French Alps

Spores of coprophilous fungi, especially Sporormiella, are often well preserved in lake sediment cores. It has been hypothesized that such spores can be used to quantify past livestock abundance. The quantitative relationship between fungal spore abundance and livestock populations, however, is not well established, nor are the mechanisms of spore transport and deposition in lacustrine systems. Multiple cores from Lake Allos, a large high-elevation lake in the French Alps, were used to map the modern abundance of Sordaria and Sporormiella spores throughout the lake. We observed high spatial heterogeneity with respect to spore numbers. No correlation with the distance from shoreline was found. There was, however, a relation with distance from the two main lake inlets. These results were used to select two fungi-rich sediment cores to investigate grazing pressure over the last two centuries. Comparisons were made between spore influx and historic data on livestock densities in the catchment. A sharp decrease in Sporormiella influx ca. 1894–1895 was associated with a reported reduction in sheep in the Allos catchment at that time. Mean influx of Sporormiella decreased by a factor of three between the nineteenth and twentieth centuries, reflecting a reduction in the reported number of animals in the Lake Allos catchment, from 6,000 to 2,000. This study confirmed that Sporormiella spore abundance in lake sediments can be used as a proxy for catchment herbivore numbers in paleoecological reconstructions. Nevertheless, our data indicate that before spore accumulation can be used to infer past domestic herbivore density, one must understand the processes of coprophilous spore transfer from the catchment to the lake and the influence of core location on spore numbers in the sediment.     

Climate change and community resilience in Samoa

Being resilient in the face of climate change seems especially important for island societies, which face the effects of rising temperatures, unpredictable rainfall, changing wind patterns and sea level rise. To date, most studies of adaptation and resilience among Pacific island communities have used indicators and methods rooted in Western science and neo-classical economics. These have been criticized as being locally irrelevant and inadequate to appreciate the dynamic nature and social structures of island communities and their capacity to adapt. This paper challenges the paradigm that defines resilience as a return to equilibrium, by using a non-equilibrium, cultural ecological lens. The non-equilibrium view of resilience sees the social systems of island nations as highly dynamic and undergoing persistent adaptation in the face of changing environmental factors. Field-based research undertaken in eight villages in Samoa found that, through constant exposure to environmental change over extended periods of time, communities have become resilient and are in a position to adapt to future changes. In developing future policy in relation to climate change, Pacific island governments need to develop a more nuanced understanding of islanders’ perceptions and historical actions in the context of both their physical locations and their dynamic socio-cultural systems.     

A Mw 6.3 earthquake scenario in the city of Nice (southeast France): ground motion simulations

The southern Alps–Ligurian basin junction is one of the most seismically active zone of the western Europe. A constant microseismicity and moderate size events (3.5 < M < 5) are regularly recorded. The last reported historical event took place in February 1887 and reached an estimated magnitude between 6 and 6.5, causing human losses and extensive damages (intensity X, Medvedev–Sponheuer–Karnik). Such an event, occurring nowadays, could have critical consequences given the high density of population living on the French and Italian Riviera. We study the case of an offshore Mw 6.3 earthquake located at the place where two moderate size events (Mw 4.5) occurred recently and where a morphotectonic feature has been detected by a bathymetric survey. We used a stochastic empirical Green’s functions (EGFs) summation method to produce a population of realistic accelerograms on rock and soil sites in the city of Nice. The ground motion simulations are calibrated on a rock site with a set of ground motion prediction equations (GMPEs) in order to estimate a reasonable stress-drop ratio between the February 25th, 2001, Mw 4.5, event taken as an EGF and the target earthquake. Our results show that the combination of the GMPEs and EGF techniques is an interesting tool for site-specific strong ground motion estimation.     

山东蓬莱新生代岩石圈地幔的异常锂同位素组成：橄榄岩包体的离子探针分析

应用离子探针技术对山东蓬莱新生代玄武岩中橄榄岩包体的主要组成矿物进行了原位测定,结果显示了强烈偏离正 常地幔矿物组成和平衡的Li 含量和同位素比值。橄榄石、斜方辉石和单斜辉石的Li 含量和δ7Li 分别为（2.0~10.4）×10-6, （2.8~23.8）×10-6 和（3.3~59.7）×10-6;-28.6‰ ~+0.5‰,-12.7‰ ~+12.8‰和-41.5‰ ~+22.6‰。这种强烈的非平衡体系反 映了最近强烈和复杂的地幔交代作用。辉石的高Li（~ 60×10-6）和δ7Li（~ +20‰）反映了最近富Li地幔熔体/ 流体的特征, 而橄榄石的中等Li 富集（<5×10-6）和强烈的δ7Li 亏损（~ -20‰）则可能记录了更早一期低δ7Li 的地幔交代。同位素剖面 的扩散反演以及Li 强烈富集与LREE 相对亏损之间的解耦显示了两期地幔交代作用的短暂性和近期性。因此,我们认为华 北东部克拉通上地幔中存在与再循环有关的锂同位素异常组分,它们的形成应该与中生代以来太平洋板块向东亚大陆下的 俯冲有关. 这些组分能够在地幔中较长的保存直至最近被热扰动所释放,并被橄榄岩包体所记录。     

Astrodynamical Space Test of Relativity Using Optical Devices I (ASTROD I)—A class-M fundamental physics mission proposal for Cosmic Vision 2015–2025

ASTROD I is a planned interplanetary space mission with multiple goals. The primary aims are: to test general relativity with an improvement in sensitivity of over three orders of magnitude, improving our understanding of gravity and aiding the development of a new quantum gravity theory; to measure key solar system parameters with increased accuracy, advancing solar physics and our knowledge of the solar system; and to measure the time rate of change of the gravitational constant with an order of magnitude improvement and the anomalous Pioneer acceleration, thereby probing dark matter and dark energy gravitationally. It is an international project, with major contributions from Europe and China and is envisaged as the first in a series of ASTROD missions. ASTROD I will consist of one spacecraft carrying a telescope, four lasers, two event timers and a clock. Two-way, two-wavelength laser pulse ranging will be used between the spacecraft in a solar orbit and deep space laser stations on Earth, to achieve the ASTROD I goals. A second mission, ASTROD (ASTROD II) is envisaged as a three-spacecraft mission which would test General Relativity to 1 ppb, enable detection of solar g-modes, measure the solar Lense–Thirring effect to 10 ppm, and probe gravitational waves at frequencies below the LISA bandwidth. In the third phase (ASTROD III or Super-ASTROD), larger orbits could be implemented to map the outer solar system and to probe primordial gravitational-waves at frequencies below the ASTROD II bandwidth.

Microfocus X-ray computed tomography analysis of corroded glass objects

Microfocus X-ray computed tomography (µCT) is a useful tool for non-destructive analysis of corroded archaeological glass objects and for monitoring restoration and conservation processes for these materials. This was demonstrated by µCT analysis of artificially corroded laboratory-produced glasses and corroded archaeological glasses retrieved from soil environments. Corrosion layers with a thickness of 20 µm or more can be detected as areas with lower X-ray attenuation values than the non-corroded glass. Features that are revealed by µCT analyses include the degree and patterns of corrosion and the presence of various internal structures in the corrosion layers. The study of restored corroded glasses demonstrates that mechanical and laser cleaning can be monitored efficiently. The study of consolidation practices, using test objects, requires the use of additives to increase X-ray attenuation values of the organic compounds that are used.